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El contenido de 10 B puede ser tan bajo como 19,1% y tan alto como 20,3% en muestras naturales. 11 B es el resto en tales casos. [2] | ||||||||||||||||||||||||
Peso atómico estándar A r, estándar (B) |
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El boro ( 5 B) se encuentra naturalmente como isótopos 10 B y 11 B, el último de los cuales constituye aproximadamente el 80% del boro natural. Hay 13 radioisótopos que se han descubierto, con números de masa de 7 a 21, todos con vidas medias cortas , siendo la más larga la de 8 B, con una vida media de solo 770 milisegundos (ms) y 12 B con media vida útil. -vida de 20,2 ms. Todos los demás isótopos tienen vidas medias inferiores a 17,35 ms. Aquellos isótopos con masa por debajo de 10 se descomponen en helio (a través de isótopos de berilio de vida corta para 7 B y 9B) mientras que aquellos con una masa superior a 11 se convierten en su mayoría en carbono .
Lista de isótopos [ editar ]
Nuclido [4] [n 1] | Z | norte | Masa isotópica ( Da ) [5] [n 2] [n 3] | Vida media [ ancho de resonancia ] | Modo de caída [n 4] | Hija isótopo [n 5] | Spin y paridad [n 6] [n 7] | Abundancia natural (fracción molar) | |
---|---|---|---|---|---|---|---|---|---|
Energía de excitación | Normal proportion | Range of variation | |||||||
7B | 5 | 2 | 7.029712(27) | 570(14) × 10−24 s [801(20) keV] | p | 6 Be [n 8] | (3/2−) | ||
8B[n 9] | 5 | 3 | 8.0246073(11) | 770(3) ms | β+, α | 2 4 He | 2+ | ||
9B | 5 | 4 | 9.0133296(10) | 800(300) × 10−21 s [0.54(21) keV] | p, α | 2 4 He | 3/2− | ||
10B[n 10] | 5 | 5 | 10.012936862(16) | Stable | 3+ | 0.199(7) | 18.929–20.386 | ||
11B | 5 | 6 | 11.009305167(13) | Stable | 3/2− | 0.801(7) | 79.614–81.071 | ||
12B | 5 | 7 | 12.0143526(14) | 20.20(2) ms | β− (98.4%) | 12 C | 1+ | ||
β−, α (1.6%) | 8 Be [n 11] | ||||||||
13B | 5 | 8 | 13.0177800(11) | 17.33(17) ms | β− (99.72%) | 13 C | 3/2− | ||
β−, n (0.28%) | 12 C | ||||||||
14B | 5 | 9 | 14.025404(23) | 12.5(5) ms | β− (93.96%) | 14 C | 2− | ||
β−, n (6.04%) | 13 C | ||||||||
15B | 5 | 10 | 15.031088(23) | 9.93(7) ms | β−, n (93.6%) | 14 C | 3/2− | ||
β− (6.0%) | 15 C | ||||||||
β−, 2n (0.4%) | 13 C | ||||||||
16B | 5 | 11 | 16.039842(26) | > 4.6 × 10−21 s | n | 15 B | 0− | ||
17B[n 12] | 5 | 12 | 17.04693(22) | 5.08(5) ms | β−, n (63.0%) | 16 C | (3/2−) | ||
β− (22.1%) | 17 C | ||||||||
β−, 2n (11.0%) | 15 C | ||||||||
β−, 3n (3.5%) | 14 C | ||||||||
β−, 4n (0.4%) | 13 C | ||||||||
18B | 5 | 13 | 18.05560(22) | < 26 ns | n | 17 B | (2−) | ||
19B[n 12] | 5 | 14 | 19.06417(56) | 2.92(13) ms | β−, n (71%) | 18 C | 3/2−# | ||
β−, 2n (17%) | 17 C | ||||||||
β− (12%) | 19 C | ||||||||
20B[6] | 5 | 15 | 20.07348(86)# | [2.50(9) MeV] | n | 19 B | (1−, 2−) | ||
21B[6] | 5 | 16 | 21.08302(97)# | < 260 ns [2.47(19) MeV] | 2n | 19 B | (3/2−)# |
- ^ mB – Excited nuclear isomer.
- ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
- ^ Modes of decay:
n: Neutron emission p: Proton emission - ^ Bold symbol as daughter – Daughter product is stable.
- ^ ( ) spin value – Indicates spin with weak assignment arguments.
- ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
- ^ Subsequently decays by double proton emission to 4He for a net reaction of 7B → 4He + 3 1H
- ^ Has 1 halo proton
- ^ One of the few stable odd-odd nuclei
- ^ Immediately decays into two α particles, for a net reaction of 12B → 3 4He + e−
- ^ a b Has 2 halo neutrons
- Neutrinos from boron-8 beta decays within the sun are an important background to dark matter direct detection experiments.[7] They are the first component of the neutrino floor that dark matter direct detection experiments are expected to eventually encounter.
Applications[edit]
Boron-10[edit]
Boron-10 is used in boron neutron capture therapy as an experimental treatment of some brain cancers.
References[edit]
- ^ a b "Atomic Weights and Isotopic Compositions for All Elements". National Institute of Standards and Technology. Retrieved 2008-09-21.
- ^ Szegedi, S.; Váradi, M.; Buczkó, Cs. M.; Várnagy, M.; Sztaricskai, T. (1990). "Determination of boron in glass by neutron transmission method". Journal of Radioanalytical and Nuclear Chemistry Letters. 146 (3): 177. doi:10.1007/BF02165219.
- ^ Meija, Juris; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry. 88 (3): 265–91. doi:10.1515/pac-2015-0305.
- ^ Half-life, decay mode, nuclear spin, and isotopic composition is sourced in:
Audi, G.; Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S. (2017). "The NUBASE2016 evaluation of nuclear properties" (PDF). Chinese Physics C. 41 (3): 030001. Bibcode:2017ChPhC..41c0001A. doi:10.1088/1674-1137/41/3/030001. - ^ Wang, M.; Audi, G.; Kondev, F. G.; Huang, W. J.; Naimi, S.; Xu, X. (2017). "The AME2016 atomic mass evaluation (II). Tables, graphs, and references" (PDF). Chinese Physics C. 41 (3): 030003-1–030003-442. doi:10.1088/1674-1137/41/3/030003.
- ^ a b Leblond, S.; et al. (2018). "First observation of 20B and 21B". Physical Review Letters. 121 (26): 262502–1–262502–6. arXiv:1901.00455. doi:10.1103/PhysRevLett.121.262502. PMID 30636115.
- ^ Cerdeno, David G.; Fairbairn, Malcolm; Jubb, Thomas; Machado, Pedro; Vincent, Aaron C.; Boehm, Celine (2016). "Physics from solar neutrinos in dark matter direct detection experiments". JHEP. 2016 (5): 118. arXiv:1604.01025. Bibcode:2016JHEP...05..118C. doi:10.1007/JHEP05(2016)118.